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ID persistente del dataset
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doi:10.21950/MVYQII |
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Fecha de publicación
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2024-09-26 |
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Título
| Main advances in the application of scorpionate-based catalytic systems for the preparation of sustainable polymers |
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Autor
| Sánchez-Barba, Luis F. (URJC) - ORCID: 0000-0001-7188-4526
Garcés, Andrés (URJC) - ORCID: 0000-0002-4484-6230
Lara-Sánchez, Agustín (Universidad de Castilla-La Mancha) - ORCID: 0000-0001-6547-4862
Navarro, Marta (Universidad de Castilla-La Mancha) - ORCID: 0000-0001-6021-0649
González-Lizana,David (URJC) - ORCID: 0000-0001-6465-3017 |
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Contacto
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Utilice el botón de e-mail de arriba para contactar.
Sánchez-Barba Merlo, Luis Fernando (URJC)
Garcés Osado, Andrés (URJC)
Lara-Sánchez, Agustín (Universidad de Castilla-La Mancha) |
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Descripción
| This database organizes references from the review article according to its sections. The first section includes references from the article's introduction, accompanied by brief comments highlighting relevant information from each citation. In the second section, we discuss citations included in the introductions of each section of the article. Additionally, the document contains separate tabs with detailed information on catalysts reviewed in the article, providing relevant data on activity, temperature, load, and other key parameters. (2024-09-26) |
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Materia
| Química |
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Palabra clave
| Organometallic Chemistry
Inorganic Chemistry
Scorpionates-based catalysts
ROP Lactide
CO2 fixation processes
Sustainable Bioresourced Processes
Biosustainable polymers |
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Publicación relacionada
| This work is a review related to this previous review about the wide range of catalytic applications of Scorpionate-systems : L. M. D. R. S. Martins, Inorg. Chim. Acta, 2022, 541, 121069
Description of the project
Scorpionate ligands have emerged as pivotal components in the field of coordination chemistry and catalysis since the seminal work by Trofimenko in the late 1960s, due to their extraordinary rich tridentate coordination chemistry, which enhances the stability of metal complexes, in conjunction with the possibility to modify the chemical and electronical features of these k3-ligands, offering a wide variety of potential substrates with multiple donor atoms. Furthermore, this type of ligand has shown wide versatility in its coordination mode and can behave as ligands with different coordination modes, which expands its possibilities as universal ligands. This review provides a comprehensive overview of the main advances in exploring scorpionate complexes based on the tris(1H-pyrazol-1-yl)borate and bis(1H-pyrazol-1-yl)methane moieties, which have been recently reported as efficient catalysts for the synthesis of sustainable polymers, specifically focused in the preparation of biorenewable polylactides (PLAs), others polyesters and polycarbonates (PCs), derived from cyclohexene carbonate, polylactide-alt-polycarbonate copolymers and alternative sustainable polymeric materials. Thus, we have approached this work by selecting and classifying the most well-performed scorpionate catalyst system, including di- (magnesium, calcium and zinc,) and tri-valent (Rare-Earth and 13 groups) and other metals (zirconium), for each of the catalytic processes mentioned above. This review represents the first contribution that summarizes the current state of the art related to the use of scorpionate-based systems, illustrating their potential as efficient catalysts for the preparation of any sustainable polymer chemistry. It finally aims to guide future research towards the development of more eco-friendly catalytic processes in promoting sustainable polymers to achieve relevant commodities. |
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Notas
| This article does not include Supporting Information, as it is a review that summarizes results from previous publications |
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Información de la subvención
| MCIN/AEI/10.13039/501100011033: PID2020-117788RB-I00
MCIN/AEI: RED2022-134287-T
Junta de Comunidades de Castilla-La Mancha and by the EU through “Fondo Europeo de Desarollo Regional” (FEDER): SBPLY/21/180501/000132 and SBPLY/22/180502/000059
Universidad de Castilla-La Mancha: 2021-GRIN-31240 |
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Depositante
| Silva, Fernando |
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Fecha de depósito
| 2024-09-26 |
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Software
| Excel |
