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Oct 31, 2024
Paramio, Irene; Merino, Paula; Torres, Tomás; De la Torre, Gema, 2024, "Subphthalocyanine metallo-organic cage as catalytic molecular photoreactor for the functionalization of fullerenes (dataset)", https://doi.org/10.21950/STJAKG, e-cienciaDatos, V1
Subphthalocyanines (SubPcs) are aromatic chromophores with a bowlshaped structure and outstanding optoelectronic properties. The cavity formed by a C3-symmetry trispyridyl-SubPc, Pd(II)-metalloorganic capsule has proved an optimal, shape-complementary space for the complexation of C60. Taking advantage of the intense green light absorption of the S...
Oct 31, 2024
Salazar, Ainhoa; Labella, Jorge; Kumar, Sunit; Torres, Tomás; De la Torre, Gema, 2024, "Acceleration of the Diels-Alder reaction between 9-functionalized anthracenes and C60/C70 in the cavity of a water soluble (dataset)", https://doi.org/10.21950/9MBDR9, e-cienciaDatos, V1
Herein we report on the acceleration of the Diels-Alder reaction between a series of 9- functionalized anthracenes and C60/C70 encapsulated in a water-soluble metallo-organic Pd(II)-subphthalocyanine cage (SubPc-cage), which performs as a catalytic molecular reactor that provides a beneficial hydrophobic environment. Negatively and positively charg...
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